What is a Lithium Battery?
A battery is made up of an anode, a cathode and two current collectors (positive and negative). Lithium ions move from the anode to the cathode via the electrolyte and back during charging.
To prevent short circuits, lithium-ion batteries use a permeable membrane called a separator that separates the electrodes. But dendrite growth in these separators can block pores and short out the battery.
High Energy Density
A lithium battery is able to provide an impressive amount of energy for its size. This is because the battery can hold a large amount of power without taking up much space or weight, which allows it to be used in a variety of applications, such as electric vehicles and medical devices.
Energy density is a key indicator of how powerful a battery is, and it can be measured in Wh/kg. This is an important metric for electric vehicles, as it helps them travel farther on a single charge than they would otherwise.
The energy density of a lithium battery depends on several factors, including the type of cathode material and the production technology that is used to produce it. Generally, the higher the energy density of a lithium battery, the more energy it can deliver over time.
Various types of batteries are available on the market, and there are many different chemistries, all with their own unique characteristics. In particular, there are three main categories of lithium ion batteries: LTO (lithium titanate), NMC (nickel manganese cobalt oxide) and Phosphate-based.
LTO batteries are one of the oldest types of lithium-ion batteries and have an energy density of 50-80 Wh/kg. The chemistry of these batteries uses lithium titanate in the anode, which helps the battery to charge quickly and handle high currents safely. However, this chemistry isn’t the best choice for most applications.
NMC batteries are another popular type of lithium-ion battery and have an energy density of 150-220 Wh/kg. These batteries use nickel and manganese in the cathode to add stability to the chemistry and help it to withstand higher temperatures and overcharge.
The energy density of a lithium battery is determined by the battery’s cathode material, the electrolyte that is used to transport lithium ions from the anode to the cathode, and the technology that is used to make the cells. This can include the use of a non-aqueous electrolyte, a metal separator, and the thickness of the foil that is used to separate the anode and cathode materials. The more advanced the production technology, the more energy density a lithium battery can have.
Extremely Long Lifespan
The lithium battery is one of the most efficient Lithium Battery electric energy storage systems available today. Its high energy density, high power-to-weight ratio, and good high-temperature performance make it ideal for use in most consumer electronic devices such as mobile phones and laptops.
Lithium batteries are also very environmentally friendly, as most can be recycled once they have served their purpose. Nevertheless, the life of a lithium battery can be significantly shortened by excessive heat and other environmental factors.
Many manufacturers estimate that lithium batteries will last 2,000 to 3,000 charge cycles before losing their original capacity. However, this figure is likely to vary according to the specific chemistry used in the battery and the way it is cared for.
In addition to the charge cycle, other factors impact a battery’s lifespan, such as the rate of internal resistance and self-discharge. Using and recharging a battery frequently can accelerate its degradation.
Another way to increase a lithium battery’s lifespan is by properly storing it. Keep the battery in a cool, dry place and leave it on a partial charge of around 40% to 50%. This will allow the battery to rest and recover.
Additionally, the battery should be kept in a room that is at or below 30 degrees Celsius (86 degrees Fahrenheit). Excessive heat can deteriorate lithium batteries, and keeping them out of direct sunlight can also extend their lifespan.
It is also recommended that a lithium battery be charged and discharged in the same charge pattern to ensure its efficiency. This is known as cycling and it has been shown to increase a battery’s lifespan by up to 30%.
A study conducted by a team of researchers at the University of Michigan found that EV batteries can be designed to extend their lifespan through the optimization of temperature, charging and discharging patterns. This can significantly decrease the negative impact that these conditions have on battery degradation, and can also help reduce greenhouse gas emissions.
Extremely Lightweight
The lithium battery is a light and energy-packed power source that can be found in many electronic devices. Its lightness makes it ideal for use in portable applications, such as e-readers and smartphones, where it can save space and weight while still providing sufficient power.
For a long time, scientists have been trying to develop an entirely new kind of rechargeable lithium battery that is more lightweight and safer than the current version. To do this, they would need to replace the liquid electrolyte with a much thinner layer of solid ceramic material, and replace one electrode with metallic lithium metal.
But a recent discovery by researchers at MIT could finally unlock the door to this technology, thanks to a new approach to lithium battery design. This new method eliminates the need for flammable liquid electrolytes, and it allows the development of batteries that can be shaped into any shape.
This new design is particularly promising for future applications because it uses solid electrolyte and metallic lithium electrodes to pack more energy into a given volume and weight than currently available. Unfortunately, this approach also has a major flaw: it can lead to the growth of dendrites, which are very difficult to break up and consume energy during discharge.
Fortunately, the research team at MIT has discovered a way to solve this problem without losing the benefits of the new battery design. They’ve identified a new kind of current collector that can be made from thin, light metal foils that are deposited in the lithium electrodes.
These metal foils are important because they allow the electrons to travel from the negative to the positive electrode, and they support the mechanical strength of the lithium electrodes. In order to reduce the weight of these metallic foils, they must be manufactured from a very pure metal such as copper or aluminum, but this can be costly and hard to do, due to its impurities.
Moreover, they are extremely durable. This means that they can withstand extreme weather conditions and intense use without being damaged. This makes them especially suitable for applications that need to run continuously in a rugged environment, such as offroad racing or overlanding.
Extremely Fast Charging
In the quest to develop more fuel-efficient and environmentally friendly electric vehicles, a fast charge speed is considered an essential component. Currently, most batteries take fifty minutes to fully charge at an average rate of about 80% SoC. This can be a huge barrier to mass adoption of battery electric vehicles and does not help address the issue of «range anxiety,» or the fear that an EV may not be able to travel long distances.
In response, researchers have been experimenting with charging protocols to achieve an optimum charging time that minimizes the charging loss and optimizes efficiency. They have also attempted to avoid low-temperature charging, which accelerates degradation and shortens Lithium Battery battery cycle life, due to its effect on polarization, internal short circuits, and lithium plating at the anode.
Using this strategy, researchers have been able to charge a Li-ion cell from 0% SOC to 80% SoC in a matter of minutes. They did this by heating the battery to a temperature that prevented lithium plating, while limiting the growth of solid electrolyte interphase (SEI), which can occur at high temperatures.
However, this method can lead to cathode particle cracking and electrolyte side reactions, as well as lithium plating at the anode. Moreover, the high charging rate can lead to battery overheating and electrode variability.
A team of engineers at UC San Diego has developed a new approach to speed up the charging process for lithium-metal batteries. Their method, published in Nature Energy on February 9, 2023, enables the charging of lithium-metal cells in less than an hour, a significant advance that can significantly break down barriers to EV adoption.
The team’s patented Si-NanowireTM anode is a thin, lightweight, highly conductivity anode that improves the charge transfer rate between the lithium ions and the electrode. Its extremely low tortuosity allows for faster charge times and higher capacity.
These findings are encouraging and indicate that a new charging protocol can be developed that addresses all the limitations of current charging protocols, such as high C-rate charging, which leads to accelerated aging and decreases battery life. The new protocol can be applied to both lithium-ion and graphite-based batteries.